e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Regiospecific coordination of ambidentate tetrazoles to cobalt oximes
…, NW Alcock, RA Henry, JH Nelson
Index: Takach, Nicolas E.; Holt, Elizabeth M.; Alcock, Nathaniel W.; Henry, Ronald A.; Nelson, John H. Journal of the American Chemical Society, 1980 , vol. 102, # 9 p. 2968 - 2979
Abstract: A series of complexes of the type (n-Bu3P) Co (DH) 2 (5R-tetrazolate)(DH is the monoanion of dimethylglyoxime; R= CF3, CH3, CsHs, C6HsCH2,(CH3) 2N, 4-FCtjH4, and 3- FCtjH4) have been prepared and characterized by conductance studies, elemental analyses, and'H,'3C (1H], 31P {1H1, and I9F NMR spectroscopy. Quantum-mechanical calculations (MIND0/3) indicate that the NI nitrogens of the aromatic tetrazolate anion are ...
