Abstract The addition of maleic anhydride to phthalazine is confirmed to form a five- membered pyrrolidino ring fusion to phthalazine VI, rather than a pyridophthalazine II, by means of synthetic and degradative experiments, and proton and carbon-13 nmr. Two of probable three isomers obtained have been isolated and the stereochemistry partially established. Comparison of the data obtained for this adduct with the data obtained for the ...