Kinetics and mechanism of bromine addition to derivatives of unsaturated aliphatic carboxylic acids in aqueous solution.

SA Mohamed Farook, S Viswanathan…

Index: Mohamed Farook, Syed Ahamed; Viswanathan, Seshaiyer; Ganesan, Ramachandran Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 5 p. 1394 - 1400

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Citation Number: 5

Abstract

This paper deals with the kinetics of bromine addition to unsaturated compounds in presence of added bromide ions at 22, 30, 38, 46, and 54° C. The substrates used were acrylamide (AAm), methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA), t-butyl acrylate (tBA), methacrylamide (MAAm), methyl methacrylate (MMA), ethyl methacrylate (EMA), methyl crotonate (MC), and ethyl crotonate (EC). The kinetics was followed ...