Trifluoromethylation of Ketones and Aldehydes with Bu3SnCF3

IA Sanhueza, KJ Bonney, MC Nielsen…

Index: Motherwell, William B.; Storey, Lynda J. Journal of Fluorine Chemistry, 2005 , vol. 126, # 4 p. 491 - 498

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Citation Number: 10

Abstract

... The Journal of Organic ... Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. J. Org. Chem. ... Table b 19 F NMR yield quantified by integration against a known amount of the internal standard, 4,4′-difluorobiphenyl. Table c ...

 Related Synthetic Route
4-Bromobenzaldehyde Structure

1122-91-4

4-Bromobenzaldehyde

N,N-dimethyl-(1-phenyl-2,2,2-trifluoroethoxytrimethylsilyl)-amine Structure

445476-82-4

N,N-dimethyl-(1...

~80%

(R)-1-(4-BROMOPHENYL)-2,2,2-TRIFLUOROETHANOL Structure

80418-12-8

(R)-1-(4-BROMOP...

Benzaldehyde Structure

100-52-7

Benzaldehyde

N,N-dimethyl-(1-phenyl-2,2,2-trifluoroethoxytrimethylsilyl)-amine Structure

445476-82-4

N,N-dimethyl-(1...

~91%

1-phenyl-2,2,2-trifluoroethanol Structure

340-04-5

1-phenyl-2,2,2-...

p-Tolualdehyde Structure

104-87-0

p-Tolualdehyde

N,N-dimethyl-(1-phenyl-2,2,2-trifluoroethoxytrimethylsilyl)-amine Structure

445476-82-4

N,N-dimethyl-(1...

~68%

2,2,2-trifluoro-1-p-tolylethanol Structure

446-65-1

2,2,2-trifluoro...

Furfural Structure

98-01-1

Furfural

N,N-dimethyl-(1-phenyl-2,2,2-trifluoroethoxytrimethylsilyl)-amine Structure

445476-82-4

N,N-dimethyl-(1...

~74%

2,2,2-Trifluoro-1-furan-2-yl-ethanol Structure

70783-48-1

2,2,2-Trifluoro...


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