Synthesis of the carbohydrate moiety of bleomycin. 2, 3, 4, 6-Tetra-O-substituted D-mannose derivatives

…, KH Kim, DK Minster, T Ohgi, SM Hecht

Index: Millar, Alan; Kim, Ki Hyup; Minster, David K.; Ohgi, Tadaaki; Hecht, Sidney M. Journal of Organic Chemistry, 1986 , vol. 51, # 2 p. 189 - 196

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Citation Number: 35

Abstract

(7) Although we are unaware of the preparation of any other 1, 2, 3-0-orthoacetyl-@-D- mannop $ ranose derivative, the formation of at least one analogous rhamnose derivative in low yield was suggested by'H NMR analysis of a crude reaction mixture. See: Backinowsky, LV; Bryamova,