Organometallics

Versatility of cyclooctadiene ligands in iridium chemistry and catalysis

M Martín, E Sola, O Torres, P Plou, LA Oro

Index: Cabeza, Javier A.; Cativiela, Carlos; de Villegas, Maria D. Diaz; Oro, Luis A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 1881 - 1884

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Citation Number: 64

Abstract

The reactions of [Ir (COD)(NCCH3)(PMe3)] BF4 toward acetonitrile, trimethylphosphine, hydrosilanes, and alkynes lead to complexes containing cyclooctadiene, cyclooctadienyl, or cyclooctenyl ligands in eight different coordination modes. The repercussion of this versatile