Alkyne Oxidations by cis-Dioxoruthenium (VI) Complexes. A Formal [3+ 2] Cycloaddition Reaction of Alkynes with cis-[(Cn*)(CF3CO2) RuVIO2] ClO4 (Cn*= 1, 4, 7- …

CM Che, WY Yu, PM Chan, WC Cheng…

Index: Silva Correa, Carlos M. M. da; Fleming, Maria Daniela C. M. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 103 - 108

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Citation Number: 86

Abstract

... Journal of the ... oxidizing metal−oxo (M O) complexes are widely invoked to play a key role in many catalytic and enzymatic oxidations 1 such as the Mn(III)-catalyzed ... ε max = 2400 dm 3 mol - 1 cm - 1 ) and a weak d−d absorption at 695 nm (ε max = 50 dm 3 mol - 1 cm - 1 ). The ...