Tetrahedron letters

A convenient aminolysis of esters catalyzed by 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene (TBD) under solvent-free conditions

C Sabot, KA Kumar, S Meunier, C Mioskowski

Index: Sabot, Cyrille; Kumar, Kanduluru Ananda; Meunier, Stephane; Mioskowski, Charles Tetrahedron Letters, 2007 , vol. 48, # 22 p. 3863 - 3866

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Citation Number: 94

Abstract

Aminolysis of esters by using the organocatalyst 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene (TBD) is reported. Secondary and tertiary amides were synthesized from alkyl or aryl esters with a variety of primary and secondary amines in good to excellent yields (60–94%) under solvent-free conditions (SFC).

~90%

~91%

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