Organometallics

Aryl (trimethylsilyl) selenides as Reagents for the Synthesis of Mono-and Diselenoesters

D Taher, JF Corrigan

Index: Taher, Deeb; Corrigan, John F. Organometallics, 2011 , vol. 30, # 21 p. 5943 - 5952

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Citation Number: 5

Abstract

Silylated organoselenium reagents react under mild conditions with acid chlorides to provide a high yield route to aromatic selenoesters. The synthesis, structures, and spectroscopic properties of the selenoesters C6H5SeC (O) R (R= CH2CH3, 1; p-CH3C6H4, 2; p-C6Me4Br, 3; p-C6Me4C (O) SeC6H5, 4) and RC (O) SeFcSeC (O) R (Fc= Fe (C5H4) 2; R= CH2CH3, 5; p-CH3C6H4, 6; p-BrC6Me4, 7) and RC (O) Se (C6H4) n SeC (O) R (n= 1, ...