Synthesis and Reactivity of N-[Bis (trimethylsilyl) methyl] heterocumulenes

G Barbaro, A Battaglia, P Giorgianni…

Index: Barbaro, Gaetano; Battaglia, Arturo; Giorgianni, Patrizia; Guerrini, Andrea; Seconi, Giancarlo Journal of Organic Chemistry, 1995 , vol. 60, # 19 p. 6032 - 6039

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Citation Number: 16

Abstract

A number of N-heterocumulenes bearing the (Me3Si) zCH (BSW substituent adjacent to the terminal nitrogen atom of the heterocumulene function, namely BSM-N= C= O (2), BSM-N= C= S (3), BSMN= C= NR (4: R= BSM; 5: R= C6H5), BSM-N= C= CR'RZ (Sa: RI= RZ= C6H5; 9b: R1= H, Rz= SiMe3; 10: RI= RZ= CH3; 12: R1= H; RZ= CH3), and BSM-N= S= O (14), have been synthesized. The synthetic utility of the BSM-N-substituted heterocumulenes ...