Macro Rings. V. Transannular Effects in the 1, 4-Decamethylenebenzene Series1

DJ Cram, HU Daeniker

Index: Cram; Daeniker Journal of the American Chemical Society, 1954 , vol. 76, p. 2743,2752

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Citation Number: 37

Abstract

As part of a general investigation of transannular effectst2 the construction of a system (I) has been undertaken that permits an evaluation of the effects of a phenyl group on a function which is held by methylene chains directly over the face of the T-electron cloud thrusting out from the aromatic ring. As a preliminary to the study of the substitution, elimination, rearrangement and addition reactions in this system, the synthesis and ...