Acyl Exchange Reactions of Vicinal Triones

WH Urry, MSH Pai, CY Chen

Index: Urry,W.H. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 5342 - 5343

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Citation Number: 6

Abstract

(3) reaction 1, or by interactions of aldehydes with oxygen or peroxides. Chain propagation is represented by reactions 2a and 2b to emphasize its simplicity. Versions of reactions 2 here involve two acyl radicals IV and three triones. Exchange is effected when reactant IV in 2a is different than the product IV from the succeeding 2b. Reaction 2 is an example of an unusual radical transfer process3 that involves attack upon an internal atom in a molecule ...