Fluorescence sensing of microcracks based on cycloreversion of a dimeric anthracene moiety

YK Song, KH Lee, WS Hong, SY Cho, HC Yu…

Index: Song, Young-Kyu; Lee, Kwang-Hun; Hong, Woo-Sung; Cho, Sung-Youl; Yu, Hwan-Chul; Chung, Chan-Moon Journal of Materials Chemistry, 2012 , vol. 22, # 4 p. 1380 - 1386

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Citation Number: 27

Abstract

Novel fluorescent crack sensors have been developed based on dimeric anthracene moiety- containing polymers. Two anthracene derivatives, 9-anthraldehyde (AA) and 9- anthracenecarboxylic acid (AC), were photodimerized to obtain cyclooctane-type dimers. Crack-sensing polymers (Poly-AA and Poly-AC) were prepared by crosslinking of poly (vinyl alcohol) by using the dimers as crosslinkers. The polymers afforded transparent, hard ...