Novel fluorescent crack sensors have been developed based on dimeric anthracene moiety- containing polymers. Two anthracene derivatives, 9-anthraldehyde (AA) and 9- anthracenecarboxylic acid (AC), were photodimerized to obtain cyclooctane-type dimers. Crack-sensing polymers (Poly-AA and Poly-AC) were prepared by crosslinking of poly (vinyl alcohol) by using the dimers as crosslinkers. The polymers afforded transparent, hard ...