Tetrahedron Letters

Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO (acac) 2 catalyst

S Matsubara, K Takai, H Nozaki

Index: Matsubara, Seijiro; Takai, Kazuhiko; Nozaki, Hitosi Tetrahedron Letters, 1983 , vol. 24, # 35 p. 3741 - 3744

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Citation Number: 29

Abstract

This document does not have an outline. ... JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. ... Author links open the overlay panel. Numbers correspond to the affiliation list which can be exposed by using the show more link. ... The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. ...