1, 2, 3??Trisubstituted Indanes by Highly Diastereoselective Palladium??Catalyzed Oxyarylation of Indenes with Arylboronic Acids and Nitroxides

S Kirchberg, R Fröhlich, A Studer

Index: Kirchberg, Sylvia; Froehlich, Roland; Studer, Armido Angewandte Chemie - International Edition, 2010 , vol. 49, # 38 p. 6877 - 6880

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Citation Number: 43

Abstract

Palladium-catalyzed oxidative difunctionalization of olefins is a heavily investigated field of research [Eq.(1)].[1] Dioxygenations,[2] diamidations,[3] and oxyamidations [4] have been realized. However, compared to difunctionalization, in which two heteroatom-containing groups are added to the olefin, and even when considering metals other than palladium, there are only very few reports on intermolecular metalmediated oxidative ...