ARKIVOC

Promoters for Pd-catalyzed methoxycarbonylation of vinyl acetate

IA Shuklov, NV Dubrovina, J Schulze, W Tietz…

Index: Arkivoc, , vol. 2012, # 3 p. 66 - 75

Full Text: HTML

Citation Number: 1

Abstract

... p-TsOH (Table 6). Methoxycarbonylation with Pd(OAc)2 gave poor conversion and did not lead to the desired product (Runs 1,2). Much better results were obtained with PdCl2, Pd(PPh3)2Cl2 anda corresponding benzonitrile complex (Runs 3-8 ... ARKIVOC 2012 (iii) 66-75 ...