1, 3, 5-Trialkyl-hexahydro-1, 3, 5-triazines–N-methylenealkylamines equilibria. 1 H NMR studies in solutions

A Adamczyk-Woźniak, K Bujnowski…

Index: Adamczyk-Wozniak, Agnieszka; Bujnowski, Krzysztof; Sporzynski, Andrzej Journal of Molecular Structure, 2008 , vol. 892, # 1-3 p. 177 - 181

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Abstract

The behavior of 1, 3, 5-trialkyl-1, 3, 5-hexahydrotriazines (A) in a variety of solvents was investigated by 1H NMR. A are stable for linear alkyls in deuterated solvents such as chloroform, benzene, acetone, dioxane, dimethylsulfoxide and acetonitrile. In case of branched alkyls, A are in equilibrium with N-methylenealkylamines (B). The A/B ratio depends on solvent, concentration of the sample and temperature. A react easily with ...