Synthesis and tautomerization study of pseudonitrosites to 1, 2-nitroximes

A Shaabani, HR Bijanzadeh, AR Karimi…

Index: Shaabani, Ahmad; Bijanzadeh, Hamid Reza; Karimi, Ali Reza; Teimouri, Mohammad Bagher; Soleimani, Kamal Canadian Journal of Chemistry, 2008 , vol. 86, # 3 p. 248 - 252

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Citation Number: 5

Abstract

4-R-Substituted 2-nitro-1-nitrosoethylbenzenes (R= H, CH3, OCH3, Cl, F) have been synthesized under solvent-free conditions and the mechanism of their tautomerization to 2- isonitroso-1-nitro-2-phenylethanes have been investigated by 1H NMR spectroscopy. Key words: tautomerization, pseudonitrosite, mechanism, 2-nitro-1-nitrosoethylbenzene, 1H NMR spectroscopy