The Journal of Organic Chemistry

Iminosulfuranes (sulfilimines). V. Thermolysis of N-acetyliminodialkylsulfuranes

H Kise, GF Whitfield, D Swern

Index: Kise,H. et al. Journal of Organic Chemistry, 1972 , vol. 37, p. 1125 - 1128

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Citation Number: 14

Abstract

The thermolysis of N-acetyliminodialkylsulfuranes, R1R2SfN-COCH8 (R'= CH3, R 2= CZH~; R'= R2= CZHE; R1= R2= n-C3H7; R1= R2= i-C8H7), in xylene affords olefin (ethylene or propylene) and N-(alky1thio) acetamides, RSNHCOCH,(R= CH3, CzHs, n-C3H7, i-C3H7), a series of new compounds. When thermolysis is carried out without solvent, intermolecular reactions also occur. In the case of the dimethyl ylide, thermolysis products include ...