Synthesis and ethylene trimerisation capability of new chromium (II) and chromium (III) heteroscorpionate complexes

AFR Kilpatrick, SV Kulangara, MG Cushion…

Index: Dalton Transactions, , vol. 39, # 15 p. 3653 - 3664

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Citation Number: 23

Abstract

... DOI: 10.1039/B926333K (Paper) Dalton Trans., 2010, 39, 3653-3664 ... 2 N(H)R (R = i Pr or Ph) or (Me 2 pz) 2 CHSiMe 2 NMe 2 with CrCl 3 (THF) 3 or CrCl 2 (THF) 2 gave Cr{(Me 2 pz) 2 CHSiMe 2 NR 1 R 2 }Cl 3 (R 1 = H, R 2 = i Pr (10) or Ph (11); R 1 = R 2 = Me (15)) or Cr ...