e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Journal of the Chemical Society C: Organic
Free-radical reactions of halogenated bridged polycyclic compounds. Part IX. The addition of methanethiol and bromotrichloromethane to 1, 4, 7, 7-tetrachloronorborn- …
DI Davies, PJ Rowley
Index: Davies,D.I.; Rowley,P.J. Journal of the Chemical Society [Section] C: Organic, 1969 , p. 424 - 429
The addition of methanethiol to 1, 4, 7, 7-tetrachloronorborn-2-ene affords 1, 4, 7, 7- tetrachloronorborn-2-endo-yl methyl sulphide, which is formed by endo attack of methylthio- radicals. The addition of bromotrichloromethane gives 3-endo-bromo-1, 4, 7, 7-tetrachloro-2- exo-trichloromethylnorbornane derived from exo attack by trichloromethyl radicals. Similar products derived from exo attack by trichloromethyl radicals are formed in the addition of ...