e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
5-Substituted and 5, 7-disubstituted 5, 7-dihydrodibenzo [c, e] thiepins and the corresponding S-oxygenated compounds: Alkylamines, carboxylic acids, and …
…, J Holubek, M Ryska, I Koruna…
Index: Sindelar, Karel; Holubek, Jiri; Ryska, Miroslav; Koruna, Ivan; Protiva, Miroslav Collection of Czechoslovak Chemical Communications, 1986 , vol. 51, # 12 p. 2848 - 2868
Abstract Reaction of 5, 7-dihydrodibenzo [c, e] thiepin (I) with n-butyllithium resulted in the partial sulfur extrusion and in the formation of the 9, 10-dihydrophenanthrene-9-thiolate anion (B). Its further transformations (by hydrolysis, aminoalkylation and spontaneous dehydrogenation) led to phenanthrene-9-thiol (IX), the corresponding disulfide X, and the S- (2-dimethylaminoethyl) derivatives XI and XIV. Reactions of 5-chloro-5, 7-dihydrodibenzo [ ...
![5,7-Dihydrodibenzo[c,e]thiepin Structure](https://image.chemsrc.com/caspic/417/6672-64-6.png)
![5,7-dihydrobenzo[d][2]benzothiepine 6,6-dioxide Structure](https://image.chemsrc.com/caspic/455/6672-63-5.png)
![5,7-dihydrodibenzo[c,e]thiepin 6-oxide Structure](https://image.chemsrc.com/caspic/467/69945-00-2.png)
![[1,1'-Biphenyl]-2,2'-dimethanol Structure](https://image.chemsrc.com/caspic/371/3594-90-9.png)
![N-methyl-6,6-dioxo-5,7-dihydrobenzo[d][2]benzothiepine-5-carboxamide Structure](https://image.chemsrc.com/caspic/477/110129-24-3.png)
![6,6-dioxido-5,7-dihydrodibenzo[c,e]thiepin-5-carboxylic acid Structure](https://image.chemsrc.com/caspic/053/110129-22-1.png)
![DIBENZO[C,E]OXEPIN-5(7H)-ONE Structure](https://image.chemsrc.com/caspic/005/4445-34-5.png)
![5-N,5-N,7-N,7-N-tetramethyl-6,6-dioxo-5,7-dihydrobenzo[d][2]benzothiepine-5,7-dicarboxamide Structure](https://image.chemsrc.com/caspic/439/110129-25-4.png)