Highly Efficient Sulfimidation of 1, 3??Dithianes by Cu (I) Complexes

L Giribabu, SP Singh, NM Patil, ML Kantam…

Index: Giribabu; Singh, Surya P.; Patil, Nandkumar M.; Kantam, M. Lakshmi; Gupte, Sunil P.; Chaudhari, Raghunath V. Synthetic Communications, 2008 , vol. 38, # 4 p. 619 - 625

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Abstract

Abstract A series of four Cu (I) complexes were tested for sulfimidation of 1, 3??dithianes in the presence of [N??(p??tolysulfonyl) imino] phenyliodinane (PhI= NTs) as the nitrene??transfer agent. Cu (TMPhen)(PPh3) Br is an efficient catalyst with more than 90% yield of the corresponding product with less reaction time as compared to the literature copper (I) complexes.