Oxygen-transfer reactions catalyzed by nitropalladium (II) complexes. Reactivity of bis (. mu.-chloro) bis [exo-3-(nitrosooxy) bicyclo [2.2. 1] hept-2-yl-C, N] dipalladium: …

F Chauvet, A Heumann, B Waegell

Index: Chauvet, F.; Heumann, A.; Waegell, B. Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 1916 - 1922

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Citation Number: 23

Abstract

Results Compared to the more classical Wacker oxidation system6 (Pd (I1) salt, CuClZ, nucleophile, protic solvent), the palladium nitro complex (CH3CN) zPdC1 (N0z)(1) acts as a pure oxygen-transfer~ atalyst.'~ While Andrews essentially studied stoichiometric and catalytic oxidations of monoolefin~,~~ J~*~ including the mechanism (s) of oxygentransfer reactions, 21 weaz focused our attention on the possibilities of this catalyst as a reagent in ...