β-Substituted organolithium compounds; direct preparation and reactivity

J Barluenga, J Flórez, M Yus

Index: Barluenga, Jose; Florez, Josefa; Yus, Miguel Journal of the Chemical Society, Chemical Communications, 1982 , # 20 p. 1153 - 1154

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Abstract

Very reactive organolithium compounds bearing an alkoxide function at the-position with respect to the metal are obtained by direct metallation with lithium naphthalenide at low temperature of the corresponding lithium chlorhydrin salt; the reaction of these dianions with different electrophilic agents leads to th