Dirhodium (II)??Catalyzed Intramolecular C H Amination of Aryl Azides

M Shen, BE Leslie, TG Driver

Index: Shen, Meihua; Leslie, Brooke E.; Driver, Tom G. Angewandte Chemie - International Edition, 2008 , vol. 47, # 27 p. 5056 - 5059

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Citation Number: 167

Abstract

The development of new transition-metal-catalyzed methods for selective functionalization of carbon–hydrogen bonds continues to be an active area of research.[1] Whereas many transition-metal complexes exhibit activity,[1] rhodium (II) dimers [1c, 2] are well established to react with a-diazo compounds [3, 4] or sulfonyliminoiodinanes [5, 6] to access metal carbenoids or nitrenoids, which can functionalize proximal aliphatic CÀH bonds to form ...

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