The Journal of Organic Chemistry

Perfluoroalkyl Derivatives with Functional Groups Containing Divalent Sulfur. II. Synthesis and Reactions of Perfluoroalkylthiohydrazides1

HC Brown, R Pater

Index: Brown,H.C.; Pater,R. Journal of Organic Chemistry, 1965 , vol. 30, p. 3739 - 3746

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Citation Number: 4

Abstract

Perfluoroalkylthiohydrazides, RFC (S) NHNRIR~, were synthesized by conversion of the corresponding perfluoroalkylhydrazidine, RFC (= NH) NHNRlRz, by hydrogen sulfide. The scope of the reaction was shown by examples in which the N2 substituent was hydrogen, an aromatic ring, an electron-releasing group, or an electron-attracting group; limitations of the method are also discussed. Syntheses of the intermediate hydrazidines are described. A ...