N-alkylation d'amines en catalyse homogène. Synthèse de mono-et de diamines cycliques

G Bitsi, E Schleiffer, F Antoni, G Jenner

Index: Bitsi, G.; Schleiffer, E.; Antoni, F.; Jenner, G. Journal of Organometallic Chemistry, 1989 , vol. 373, p. 343 - 352

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Citation Number: 35

Abstract

Abstract Ruthenium compounds are appropriate catalysts in the N-alkylation of amines. The synthesis of N-alkylated cyclic amines from a cyclic amine and an alcohol or via the condensation between a diol and a primary amine are described. The reaction with cyclic amines is highly selective, especially in the presence of a phosphine, making it a high yielding preparative procedure.