Formation of. alpha.-disulfoxides, sulfinic anhydrides, and sulfines during the m-chloroperoxybenzoic acid oxidation of symmetrical S-alkyl alkanethiosulfinates

F Freeman, CN Angeletakis

Index: Freeman, Fillmore; Angeletakis, Christos N. Journal of the American Chemical Society, 1983 , vol. 105, # 12 p. 4039 - 4049

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Citation Number: 49

Abstract

Abstract: The m-chloroperoxybenzoic acid (MCPBA) oxidation of S-methyl methanethiosulfinate (33), S-propyl propanethiosulfinate (34), S-2-propyl 2- propanethiosulfinate (35), S-butyl butanethiosulfinate (36), and S-(phenylmethyl) phenylmethanethiosulfinate (37) has been studied at low temperatures and compared with the MCPBA oxidation of S-(2-methyl-2-propyl) 2-methyl-2-propanethiosulfinate (26) and S ...