Action of bases on 1-mercaptopropyltrimethyl-ammonium iodide

A Ekambaram, R Thomas, DA Buckley…

Index: Ekambaram,A. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 2985 - 2987

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Citation Number: 2

Abstract

1-Mercaptopropyltrimethylammonium iodide (A) is unaltered by aqueous sodium hydroxide at 90" or by potassium t-butoxide in refluxing t-butyl alcohol; with dry potassium t-butoxide at 180" l-methylmercapto-3-dimethylaminopropane (C) is formed. Aqueous sodium hydroxide at 150" gave propionic acid, trimethylamine, methanol, and a polymer corresponding to (CH2CH~ CH2S) r. Trimethylene sulfide is not an intermediate in the reaction. The 1- ...