Mass spectral rearrangements of 3??arylsulphonyl??2??arylthiopropenes and N??(4′??arylsulphonyl??2′??butynyl)??N??(4 ″??arylthio??2 ″??butynyl) anilines

PE Glaspy, RA Hancock…

Index: Glaspy, P. E.; Hancock, R. A.; Thyagarajan, B. S. Organic Mass Spectrometry, 1985 , vol. 20, # 4 p. 281 - 287

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Citation Number: 7

Abstract

Abstract Under electron impact the title compounds undergo skeletal rearrangement in addition to the anticipated modes of cleavage. The 3-arylsulphonyl-2-arylthiopropenes readily eliminate sulphur dioxide. Other modes of fragmentation include rearrangement to ...