Journal of the American Chemical Society

The Potassium-catalyzed Reaction of Olefins with Arylalkanes1

L Schaap, H Pines

Index: Schaap; Pines Journal of the American Chemical Society, 1957 , vol. 79, p. 4967,4968

Full Text: HTML

Citation Number: 29

Abstract

Benzene and arylalkanes having no benzylic hydrogens react with ethylene only under more vigorous conditions to yield products in which the aromatic ring has been eth~ lated.~ The mode of addition of arylalkanes to substituted ethylenes has been shown to be highly selective. The compounds produced are those that

 Related Synthetic Route
ethene Structure

54509-73-8

ethene

Anthracene Structure

120-12-7

Anthracene

Toluene Structure

108-88-3

Toluene

~%

n-propylbenzene Structure

103-65-1

n-propylbenzene

Detail
3,3-Dimethyl-1-indanone Structure

26465-81-6

3,3-Dimethyl-1-...

~%

1H-Indene,2,3-dihydro-1,1-dimethyl- Structure

4912-92-9

1H-Indene,2,3-d...

Cumene Structure

98-82-8

Cumene

ethene Structure

54509-73-8

ethene

~%

1H-Indene,2,3-dihydro-1,1-dimethyl- Structure

4912-92-9

1H-Indene,2,3-d...

tert-Pentylbenzene Structure

2049-95-8

tert-Pentylbenzene

N/A Structure

253185-03-4

N/A

ethene Structure

54509-73-8

ethene

Anthracene Structure

120-12-7

Anthracene

~%

1-butan-2-yl-4-tert-butylbenzene Structure

25027-33-2

1-butan-2-yl-4-...

Cumene Structure

98-82-8

Cumene

propene Structure

187737-37-7

propene

~%

1H-Indene,2,3-dihydro-1,1,3-trimethyl- Structure

2613-76-5

1H-Indene,2,3-d...

Cumene Structure

98-82-8

Cumene

propene Structure

187737-37-7

propene

Anthracene Structure

120-12-7

Anthracene

~%

1H-Indene,2,3-dihydro-1,1,3-trimethyl- Structure

2613-76-5

1H-Indene,2,3-d...

Detail

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