2-trimethylsilylphenyl triflate

Modify Date: 2024-01-02 17:28:04

2-trimethylsilylphenyl triflate Structure
2-trimethylsilylphenyl triflate structure
Common Name 2-trimethylsilylphenyl triflate
CAS Number 88284-48-4 Molecular Weight 298.354
Density 1.3±0.1 g/cm3 Boiling Point 294.8±40.0 °C at 760 mmHg
Molecular Formula C10H13F3O3SSi Melting Point N/A
MSDS Chinese USA Flash Point 132.1±27.3 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 2-(Trimethylsilyl)phenyl trifluoromethanesulfonate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 294.8±40.0 °C at 760 mmHg
Molecular Formula C10H13F3O3SSi
Molecular Weight 298.354
Flash Point 132.1±27.3 °C
Exact Mass 298.030670
PSA 51.75000
LogP 5.28
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.470

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases 26-27-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group
HS Code 2931900090

 Synthetic Route

~92%

2-trimethylsilylphenyl triflate Structure

2-trimethylsily...

CAS#:88284-48-4

Literature: Michel, Boris; Greaney, Michael F. Organic Letters, 2014 , vol. 16, # 10 p. 2684 - 2687

~91%

2-trimethylsilylphenyl triflate Structure

2-trimethylsily...

CAS#:88284-48-4

Literature: Atkinson, Darcy J.; Sperry, Jonathan; Brimble, Margaret A. Synthesis, 2010 , # 6 p. 911 - 913

~%

2-trimethylsilylphenyl triflate Structure

2-trimethylsily...

CAS#:88284-48-4

Literature: Bronner, Sarah M.; Garg, Neil K. Journal of Organic Chemistry, 2009 , vol. 74, # 22 p. 8842 - 8843

~%

2-trimethylsilylphenyl triflate Structure

2-trimethylsily...

CAS#:88284-48-4

Literature: Chemistry Letters, , p. 1211 - 1214

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
Tandem thia-Fries rearrangement--cyclisation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate benzyne precursors.

Chem. Commun. (Camb.) 49(69) , 7602-4, (2013)

A novel transformation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate aryne precursors is described.

 Synonyms

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHYLSULFONATE
2-trimethylsilylphenyl triflate
2-(Trimethylsilyl)phenyl trifluoromethanesulfonate
(2-trimethylsilylphenyl) trifluoromethanesulfonate
2-(trimethylsilyl)phenyl triflate
MFCD00799598
Methanesulfonic acid, 1,1,1-trifluoro-, 2-(trimethylsilyl)phenyl ester