Ethyl (2E)-3-(4-ethoxyphenyl)acrylate

Modify Date: 2024-01-22 21:46:34

Ethyl (2E)-3-(4-ethoxyphenyl)acrylate Structure
Ethyl (2E)-3-(4-ethoxyphenyl)acrylate structure
Common Name Ethyl (2E)-3-(4-ethoxyphenyl)acrylate
CAS Number 75332-46-6 Molecular Weight 220.26400
Density N/A Boiling Point N/A
Molecular Formula C13H16O3 Melting Point 38-42ºC(lit.)
MSDS N/A Flash Point 230 °F

 Names

Name Ethyl (2E)-3-(4-ethoxyphenyl)acrylate
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 38-42ºC(lit.)
Molecular Formula C13H16O3
Molecular Weight 220.26400
Flash Point 230 °F
Exact Mass 220.11000
PSA 35.53000
LogP 2.66160

 MSDS

Version 1.2
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product NameETHYL TRANS-4-ETHOXYCINNAMATE, 97%

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Not hazardous according to Directive 67/548/EEC.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
ETHYL TRANS-4-ETHOXYCINNAMATE, 97% 1504-69-4 216-130-8 None
FormulaC13H16O3
Molecular Weight 227,2700 AMU

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
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Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Avoid inhalation. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Respiratory protection is not required. Where
protection is desired, use multi-purpose combination (US) or type
ABEK (EN 14387) respirator cartridges.
Hand Protection: Protective gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

AppearancePhysical State: Liquid
PropertyValueAt Temperature or Pressure
pHN/A
BP/BP RangeN/A
MP/MP Range38,000. - 42,000 °C.
Flash Point110,000 °CMethod: closed cup
FlammabilityN/A
Autoignition TempN/A
Oxidizing PropertiesN/A
Explosive PropertiesN/A
Explosion LimitsN/A
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Vapor PressureN/A
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
Non-hazardous for road transport.
IMDG
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Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.

15 - Regulatory Information

Not hazardous according to Directive 67/548/EEC.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 3
Self-Classification

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

WGK Germany 3

 Synthetic Route

~%

Ethyl (2E)-3-(4-ethoxyphenyl)acrylate Structure

Ethyl (2E)-3-(4...

CAS#:75332-46-6

Literature: Journal of the Chemical Society, , p. 4064,4068

~%

Ethyl (2E)-3-(4-ethoxyphenyl)acrylate Structure

Ethyl (2E)-3-(4...

CAS#:75332-46-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 58, p. 181,189

 Synonyms

4-ethoxy-trans-cinnamic acid ethyl ester
4-Brom-2-methyl-trans-crotonsaeure-aethylester
MFCD02683512
2-Butenoic acid,4-bromo-2-methyl-,ethyl ester,(E)
4-bromo-2-methyl-trans-crotonic acid ethyl ester
4-Aethoxy-trans-zimtsaeure-aethylester
2-Butenoic acid,4-bromo-2-methyl-,ethyl ester,(Z)
ethyl (E)-4-ethoxycinnamate
ethyl 4-bromotiglate
ethyl (E)-4-bromo-2-methylbut-2-enoate
EINECS 216-130-8
4-bromo-2-methyl-but-2-enoic acid ethyl ester
ethyl trans-4-ethoxycinnamate