Methyl (S)-N-Tritylaziridine-2-carboxylate

Modify Date: 2024-01-02 16:19:01

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure
Methyl (S)-N-Tritylaziridine-2-carboxylate structure
Common Name Methyl (S)-N-Tritylaziridine-2-carboxylate
CAS Number 75154-68-6 Molecular Weight 343.41800
Density 1.196g/cm3 Boiling Point 430.347ºC at 760 mmHg
Molecular Formula C23H21NO2 Melting Point 124-128ºC(lit.)
MSDS Chinese USA Flash Point 133.289ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Methyl (S)-N-Tritylaziridine-2-carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.196g/cm3
Boiling Point 430.347ºC at 760 mmHg
Melting Point 124-128ºC(lit.)
Molecular Formula C23H21NO2
Molecular Weight 343.41800
Flash Point 133.289ºC
Exact Mass 343.15700
PSA 29.31000
LogP 3.77360
Index of Refraction 1.623
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2933990090

 Synthetic Route

~99%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Willems, Johannes G. H.; Hersmis, Marco C.; De Gelder, Rene; Smits, Jan M. M.; Hammink, Jeannet B.; Dommerholt, F. Jan; Thijs, Lambertus; Zwanenburg, Binne Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 963 - 967

~99%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Dugave, Christophe; Menez, Andre Tetrahedron Asymmetry, 1997 , vol. 8, # 9 p. 1453 - 1465

~95%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Foley, David; Pieri, Myrtani; Pettecrew, Rachel; Price, Richard; Miles, Stephen; Lam, Ho Kam; Bailey, Patrick; Meredith, David Organic and Biomolecular Chemistry, 2009 , vol. 7, # 18 p. 3652 - 3656

~10%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Journal of Organic Chemistry, , vol. 61, # 17 p. 6067 - 6070

~98%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Dugave, Christophe; Menez, Andre Tetrahedron Asymmetry, 1997 , vol. 8, # 9 p. 1453 - 1465

~%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Synthetic Communications, , vol. 37, # 12 p. 2019 - 2030

~%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Tetrahedron, , vol. 52, # 29 p. 9891 - 9900

~%

Methyl (S)-N-Tritylaziridine-2-carboxylate Structure

Methyl (S)-N-Tr...

CAS#:75154-68-6

Literature: Experientia, , vol. 13, p. 291 Collection of Czechoslovak Chemical Communications, , vol. 22, p. 262,270

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

MFCD01863736
methyl (2S)-1-tritylaziridine-2-carboxylate