Methyldifluor(fluorsulfonyl)acetat

Modify Date: 2024-01-02 11:42:00

Methyldifluor(fluorsulfonyl)acetat Structure
Methyldifluor(fluorsulfonyl)acetat structure
Common Name Methyldifluor(fluorsulfonyl)acetat
CAS Number 680-15-9 Molecular Weight 192.114
Density 1.6±0.1 g/cm3 Boiling Point 150.0±40.0 °C at 760 mmHg
Molecular Formula C3H3F3O4S Melting Point N/A
MSDS Chinese USA Flash Point 44.5±27.3 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 150.0±40.0 °C at 760 mmHg
Molecular Formula C3H3F3O4S
Molecular Weight 192.114
Flash Point 44.5±27.3 °C
Exact Mass 191.970413
PSA 68.82000
LogP 1.85
Vapour Pressure 3.9±0.3 mmHg at 25°C
Index of Refraction 1.371

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H226-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R10;R34
Safety Phrases S26-S36/37/39-S45-S16
RIDADR UN 2920 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2915900090

 Synthetic Route

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
Evaluating the thermal vinylcyclopropane rearrangement (VCPR) as a practical method for the synthesis of difluorinated cyclopentenes: experimental and computational studies of rearrangement stereospecificity.

Chemistry 20(44) , 14305-16, (2014)

Vinyl cyclopropane rearrangement (VCPR) has been utilised to synthesise a difluorinated cyclopentene stereospecifically and under mild thermal conditions. Difluorocyclopropanation chemistry afforded e...

A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.

Angew. Chem. Int. Ed. Engl. 50 , 3793, (2011)

J. Chem. Soc. Chem. Commun. , 705, (1989)

 Synonyms

Methyl difluoro(fluorosulfonyl)acetate
methyl 2,2-difluoro-2-fluorosulfonylacetate
MFCD00144316
Methyldifluor(fluorsulfonyl)acetat
Acetic acid, 2,2-difluoro-2-(fluorosulfonyl)-, methyl ester
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