Benzenamine,N-methyl-2-nitro-

Modify Date: 2024-01-02 23:26:39

Benzenamine,N-methyl-2-nitro- Structure
Benzenamine,N-methyl-2-nitro- structure
Common Name Benzenamine,N-methyl-2-nitro-
CAS Number 612-28-2 Molecular Weight 152.15100
Density 1.26g/cm3 Boiling Point 277.9ºC at 760 mmHg
Molecular Formula C7H8N2O2 Melting Point 35-38 °C(lit.)
MSDS Chinese USA Flash Point >230 °F
Symbol GHS06 GHS08
GHS06, GHS08
Signal Word Danger

 Names

Name n-methyl-2-nitroaniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.26g/cm3
Boiling Point 277.9ºC at 760 mmHg
Melting Point 35-38 °C(lit.)
Molecular Formula C7H8N2O2
Molecular Weight 152.15100
Flash Point >230 °F
Exact Mass 152.05900
PSA 57.85000
LogP 2.23270
Index of Refraction 1.619

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: N-Methyl 2-nitroaniline
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H301:Toxic if swallowed
H311:Toxic in contact with skin
H331:Toxic if inhaled
H373:May cause damage to organs through prolonged or repeated exposure
P261:Avoid breathing dust/fume/gas/mist/vapours/spray
P280:Wear protective gloves/protective clothing/eye protection/face protection
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P311:Call a POISON CENTER or doctor/physician

Section3. Composition/information on ingredients.
Ingredient name:N-Methyl 2-nitroaniline
CAS number:612-28-2

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Not specified
Appearance:
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula:C7H8N2O2
Molecular weight:152.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN2811 Class: 6.1 Packing group: II
Proper shipping name: TOXIC SOLIDS, ORGANIC, N.O.S. (N-Methyl 2-nitroaniline)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY5710000
CHEMICAL NAME :
Aniline, N-methyl-o-nitro-
CAS REGISTRY NUMBER :
612-28-2
BEILSTEIN REFERENCE NO. :
2209110
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H8-N2-O2
MOLECULAR WEIGHT :
152.17

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
2500 ug/plate
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 23,695,1985

 Safety Information

Symbol GHS06 GHS08
GHS06, GHS08
Signal Word Danger
Hazard Statements H301 + H311 + H331-H373
Precautionary Statements P261-P280-P301 + P310-P311
Personal Protective Equipment Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard Codes T:Toxic;
Risk Phrases R23/24/25;R33
Safety Phrases S36/37-S45
RIDADR 2811
WGK Germany 3
RTECS BY5710000
Packaging Group II
Hazard Class 6.1

 Synthetic Route

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 Synonyms

Benzenamine,N-methyl-2-nitro
EINECS 210-303-1
N-Methyl-2-nitrobenzenamine
2-Nitro-N-methylaniline
Aniline,N-methyl-o-nitro
o-nitro-N-methylaminobenzene
2-methylamino-nitrobenzene
o-nitro-N-methylaniline
N-Methyl 2-nitroaniline
o-(Methylamino)nitrobenzene
N-Methyl-o-nitroaniline
MFCD00007090