Methyl (4-bromophenyl)(oxo)acetate

Modify Date: 2024-01-11 17:11:21

Methyl (4-bromophenyl)(oxo)acetate Structure
Methyl (4-bromophenyl)(oxo)acetate structure
Common Name Methyl (4-bromophenyl)(oxo)acetate
CAS Number 57699-28-2 Molecular Weight 243.054
Density 1.5±0.1 g/cm3 Boiling Point 308.5±25.0 °C at 760 mmHg
Molecular Formula C9H7BrO3 Melting Point N/A
MSDS N/A Flash Point 140.4±23.2 °C

 Names

Name methyl 2-(4-bromophenyl)-2-oxoacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 308.5±25.0 °C at 760 mmHg
Molecular Formula C9H7BrO3
Molecular Weight 243.054
Flash Point 140.4±23.2 °C
Exact Mass 241.957855
PSA 43.37000
LogP 2.21
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.554

 Safety Information

Hazard Codes Xi
HS Code 2918300090

 Synthetic Route

~70%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Guo, Zhenqiu; Huang, Haoxi; Fu, Qingquan; Hu, Wenhao Synlett, 2006 , # 15 p. 2486 - 2488

~75%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Zhuang, Jing; Wang, Changqing; Xie, Fang; Zhang, Wanbin Tetrahedron, 2009 , vol. 65, # 47 p. 9797 - 9800

~%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Sheppeck, James; Dhar, T.G. Murali; Doweyko, Lidia; Gilmore, John; Weinstein, David; Xiao, Hai-Yun; Yang, Bingwei V.; Doweyko, Arthur M. Patent: US2006/154973 A1, 2006 ; Location in patent: Page/Page column 47 ;

~94%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Banerjee, Sudheer K.; Shanker, R.; Sachdeva, Om P. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986 , vol. 41, # 4 p. 467 - 472

~55%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Cohen; Gibson; Fan; De la Cruz; Gitler; Hariman; Reba Journal of Pharmaceutical Sciences, 1992 , vol. 81, # 4 p. 326 - 329

~%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Muller, A. J.; Nishiyama, K.; Griffin, G. W.; Ishikawa, K.; Gibson, D. M. Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2342 - 2352

~%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Ma, Ming; Li, Changkun; Peng, Lingling; Xie, Fang; Zhang, Xiu; Wang, Jianbo Tetrahedron Letters, 2005 , vol. 46, # 22 p. 3927 - 3929

~0%

Methyl (4-bromophenyl)(oxo)acetate Structure

Methyl (4-bromo...

CAS#:57699-28-2

Literature: Tao, Jason; Tran, Richard; Murphy, Graham K. Journal of the American Chemical Society, 2013 , vol. 135, # 44 p. 16312 - 16315

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

methyl (p-bromophenyl)glyoxylate
Methyl (4-bromophenyl)(oxo)acetate
methyl (p-bromophenyl)glyoxalate
methyl (4-bromophenyl)-2-oxoacetate
Benzeneacetic acid, 4-bromo-α-oxo-, methyl ester
(4-bromo-phenyl)-oxo-acetic acid methyl ester
methyl (4-bromophenyl)glyoxylate
2-(4-bromophenyl)-2-oxoacetic acid methyl ester