2,6-Dimethylbromobenzene

Modify Date: 2024-01-02 09:05:16

2,6-Dimethylbromobenzene Structure
2,6-Dimethylbromobenzene structure
Common Name 2,6-Dimethylbromobenzene
CAS Number 576-22-7 Molecular Weight 185.061
Density 1.3±0.1 g/cm3 Boiling Point 204.4±9.0 °C at 760 mmHg
Molecular Formula C8H9Br Melting Point −10 °C(lit.)
MSDS Chinese USA Flash Point 73.9±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2-Bromo-1,3-dimethylbenzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 204.4±9.0 °C at 760 mmHg
Melting Point −10 °C(lit.)
Molecular Formula C8H9Br
Molecular Weight 185.061
Flash Point 73.9±0.0 °C
Exact Mass 183.988754
LogP 3.91
Vapour Pressure 0.4±0.4 mmHg at 25°C
Index of Refraction 1.544

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CY9020000
CHEMICAL NAME :
Benzene, 2-bromo-1,3-dimethyl-
CAS REGISTRY NUMBER :
576-22-7
BEILSTEIN REFERENCE NO. :
1929780
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C8-H9-Br
MOLECULAR WEIGHT :
185.08
WISWESSER LINE NOTATION :
ER B1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#07031

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant
Risk Phrases R36/37/38
Safety Phrases S26-S36-S24/25
RIDADR UN 2810
WGK Germany 3
RTECS CY9020000
Packaging Group I; II; III
Hazard Class 6.1
HS Code 2903999090

 Synthetic Route

 Customs

HS Code 2903999090
Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles1

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A versatile catalyst system for Suzuki-Miyaura syntheses of sterically hindered biaryls employing a cyclobutene-1,2-bis(imidazolium) salt.

Chem. Commun. (Camb.) 46 , 2995-2997, (2010)

The catalyst system consisting of 3,3'-(3,4-bis(dichloro-methylene)cyclobut-1-ene-1,2-diyl)bis(1-methyl-1H-imidazolium) bis(tetrafluoroborate), Pd(OAc)(2) and NaOtBu in toluene proved to be very effec...

 Synonyms

EINECS 209-397-7
2-Bromo-1,3-dimethylbenzene
2,6-Dimethyl bromobenzene
Benzene, 2-bromo-1,3-dimethyl-
2,6-dimethyl-1-bromobenzene
MFCD00000075
2-Bromo-m-xylene
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