Diethylzinc

Modify Date: 2024-01-02 18:17:15

Diethylzinc Structure
Diethylzinc structure
Common Name Diethylzinc
CAS Number 557-20-0 Molecular Weight 123.531
Density 1.205 g/mL at 25 °C(lit.) Boiling Point 98 °C
Molecular Formula C4H10Zn Melting Point −28 °C(lit.)
MSDS Chinese USA Flash Point 45 °F
Symbol GHS02 GHS05 GHS09
GHS02, GHS05, GHS09
Signal Word Danger

 Names

Name diethylzinc
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.205 g/mL at 25 °C(lit.)
Boiling Point 98 °C
Melting Point −28 °C(lit.)
Molecular Formula C4H10Zn
Molecular Weight 123.531
Flash Point 45 °F
Exact Mass 122.007393
LogP 1.94530
Index of Refraction n20/D 1.498(lit.)
Water Solubility REACTS VIOLENTLY

 Safety Information

Symbol GHS02 GHS05 GHS09
GHS02, GHS05, GHS09
Signal Word Danger
Hazard Statements H250-H260-H314-H410
Supplemental HS Reacts violently with water.
Precautionary Statements P210-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
Risk Phrases R11;R14;R17;R34;R48/20;R50/53;R62;R65;R67
Safety Phrases S26-S45-S61-S62-S8-S36/37/39-S16-S60-S43
RIDADR UN 3399 4.3/PG 1
WGK Germany 2
RTECS ZH2077777
Packaging Group I
Hazard Class 4.3

 Synthetic Route

 Articles27

More Articles
Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters.

Org. Lett. 8 , 5405, (2006)

[Structure: see text] A highly enantioselective synthesis of alpha-dehydroaminoacids with a stereogenic center in the gamma position through copper-catalyzed asymmetric conjugate addition of diethylzi...

(R)-(+)-Binol-functionalized mesoporous organosilica as a highly efficient pre-chiral catalyst for asymmetric catalysis.

Chem. Asian J. 5(5) , 1232-9, (2010)

(R)-(+)-Binol-functionalized chiral periodic mesoporous organosilicas (PMOs) with different framework compositions were successfully synthesized by cocondensation of (R)-2,2'-di(methoxymethyl)oxy-6,6'...

Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral beta-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system.

Chirality 21(2) , 316-23, (2009)

A new catalytic system, generated from the readily available and inexpensive beta-sulfonamide alcohol L*, Ti(O(i)Pr)(4), Et(2)Zn, and tertiary amine base (R(3)N), effectively catalyzes the enantiosele...

 Synonyms

Zincdiethyl
Zinc, diethyl-
Diethylzink
ZnEt2
Diethylzinc solution
EINECS 209-161-3
zinc,ethane
(C2H5)2Zn
Et2Zn
MFCD00009021
Zinc ethide
DIETHYL ZINC
Diethylzinc
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