Nitroguanidine

Modify Date: 2024-01-02 21:58:55

Nitroguanidine Structure
Nitroguanidine structure
 Common Name Nitroguanidine
CAS Number 556-88-7 Molecular Weight 104.068
Density 2.0±0.1 g/cm3 Boiling Point 219.3±23.0 °C at 760 mmHg
Molecular Formula CH4N4O2 Melting Point 239 °C (dec.)(lit.)
MSDS Chinese USA Flash Point 86.5±22.6 °C

 Names

Name Nitroguanidine
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.0±0.1 g/cm3
Boiling Point 219.3±23.0 °C at 760 mmHg
Melting Point 239 °C (dec.)(lit.)
Molecular Formula CH4N4O2
Molecular Weight 104.068
Flash Point 86.5±22.6 °C
Exact Mass 104.033424
PSA 107.72000
LogP -1.31
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.685
Water Solubility 3 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MF4600000
CHEMICAL NAME :
Guanidine, 1-nitro-
CAS REGISTRY NUMBER :
556-88-7
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C-H4-N4-O2
MOLECULAR WEIGHT :
104.09
WISWESSER LINE NOTATION :
WNMYZUM

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10200 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3850 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
48 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3120 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Fibroblast
DOSE/DURATION :
4 gm/L/24H
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 48,337,1977

 Safety Information

Supplemental HS Explosive when dry.
Personal Protective Equipment Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes F: Flammable;Xi: Irritant;
Risk Phrases R11;R36/37/38;R5
Safety Phrases S16-S26-S33-S36/37/39-S47-S37/39
RIDADR UN 1336 4.1/PG 1
WGK Germany 1
RTECS MF4600000
Hazard Class 1.1D
HS Code 2925290090

 Synthetic Route

Guanidine nitrate structure

Guanidine nitrate

CAS#:506-93-4

~99%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: GLAXO GROUP LIMITED; JIN, Yun; WAN, Zehong; ZHANG, Qing Patent: WO2012/76435 A1, 2012 ; Location in patent: Page/Page column 36 ;
Guanidine sulfate structure

Guanidine sulfate

CAS#:594-14-9

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Journal of the American Chemical Society, , vol. 55, p. 737 Nitrocell., , vol. 7, p. 143 Chem. Zentralbl., , vol. 107, # II p. 3973
Guanidine thiocyanate structure

Guanidine thioc...

CAS#:593-84-0

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Justus Liebigs Annalen der Chemie, , vol. 270, p. 44 Justus Liebigs Annalen der Chemie, , vol. 271, p. 129 DE59241 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 3, p. 16
Nitroguanylazide structure

Nitroguanylazide

CAS#:62154-79-4

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Journal of Applied Chemistry, , vol. 2, p. 368
1-Nitrosoguanidine structure

1-Nitrosoguanidine

CAS#:674-81-7

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Justus Liebigs Annalen der Chemie, , vol. 273, p. 136
Phosphoric acid structure

Phosphoric acid

CAS#:7664-38-2
Guanidine nitrate structure

Guanidine nitrate

CAS#:506-93-4

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Journal of the American Chemical Society, , vol. 55, p. 737
Hydrazinecarboximidamide,N-nitro- structure

Hydrazinecarbox...

CAS#:18264-75-0

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7

Hydrazinecarboximidamide(9CI) structure

Hydrazinecarbox...

CAS#:79-17-4
Nitrogen structure

Nitrogen

CAS#:7727-37-9
Literature: Journal of the American Chemical Society, , vol. 71, p. 1873
nitric acid structure

nitric acid

CAS#:7697-37-2
guanidine structure

guanidine

CAS#:113-00-8

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Gazzetta Chimica Italiana, , vol. 21 II, p. 405 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 88, p. 814,1086 Justus Liebigs Annalen der Chemie, , vol. 270, p. 44 Justus Liebigs Annalen der Chemie, , vol. 271, p. 129 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 85, p. 548 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 88, p. 814,1087
1-Nitrosoguanidine structure

1-Nitrosoguanidine

CAS#:674-81-7
nitric acid structure

nitric acid

CAS#:7697-37-2

~%

Nitroguanidine Structure

Nitroguanidine

CAS#:556-88-7
Literature: Justus Liebigs Annalen der Chemie, , vol. 273, p. 136

 Customs

HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles13

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[Research and determination of occupational exposure limits of nitroguanidine in air of working places].

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 Synonyms

EINECS 209-143-5
2-nitroguanidine
MFCD00007039
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