tert-Butyl methyl malonate structure
|
Common Name | tert-Butyl methyl malonate | ||
---|---|---|---|---|
CAS Number | 42726-73-8 | Molecular Weight | 174.194 | |
Density | 1.0±0.1 g/cm3 | Boiling Point | 197.7±0.0 °C at 760 mmHg | |
Molecular Formula | C8H14O4 | Melting Point | -10ºC | |
MSDS | USA | Flash Point | 79.4±0.0 °C |
Name | tert-Butyl Methyl Malonate |
---|---|
Synonym | More Synonyms |
Density | 1.0±0.1 g/cm3 |
---|---|
Boiling Point | 197.7±0.0 °C at 760 mmHg |
Melting Point | -10ºC |
Molecular Formula | C8H14O4 |
Molecular Weight | 174.194 |
Flash Point | 79.4±0.0 °C |
Exact Mass | 174.089203 |
PSA | 52.60000 |
LogP | 0.87 |
Appearance of Characters | Liquid | Clear colorless to slightly yellow |
Vapour Pressure | 0.4±0.3 mmHg at 25°C |
Index of Refraction | 1.422 |
Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
---|---|
Hazard Codes | Xi |
Safety Phrases | S23-S24/25 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2918990090 |
~94% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Smith, Alexander M. R.; Rzepa, Henry S.; White, Andrew J. P.; Billen, Denis; Hii, King Kuok Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 3085 - 3096 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Hauser; Levine; Kibler Journal of the American Chemical Society, 1946 , vol. 68, p. 27 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Hauser; Levine; Kibler Journal of the American Chemical Society, 1946 , vol. 68, p. 27 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Koskinen, Ari M. P.; Munoz, Luis Journal of Organic Chemistry, 1993 , vol. 58, # 4 p. 879 - 886 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Sato, Masayuki; Ban, Hitoshi; Kaneko, Chikara Tetrahedron Letters, 1997 , vol. 38, # 38 p. 6689 - 6692 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Becker CHEMTECH, 1957 , vol. 9, p. 477 |
~% tert-Butyl meth... CAS#:42726-73-8 |
Literature: Matoba, Katsuhide; Yamazaki, Takao Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 8 p. 2955 - 2956 |
HS Code | 2918990090 |
---|---|
Summary | 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
Stereospecific Pd(O)-catalyzed malonate additions to allylic hydroxy phosphonate derivatives: a formal synthesis of (-)-enterolactone.
J. Org. Chem. 69(8) , 2859-62, (2004) A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substitu... |
Propanedioic acid, 1,1-dimethylethyl methyl ester |
tert-butyl methylmalonate |
EINECS 255-919-1 |
MFCD00042856 |
3-O-tert-butyl 1-O-methyl propanedioate |
Methyl 2-methyl-2-propanyl malonate |
tert.-Butyl methyl malonate |
tert-Butyl methyl malonate |