potassium,trifluoromethanesulfinate

Modify Date: 2024-01-10 11:35:32

potassium,trifluoromethanesulfinate Structure
potassium,trifluoromethanesulfinate structure
Common Name potassium,trifluoromethanesulfinate
CAS Number 41804-89-1 Molecular Weight 172.16800
Density N/A Boiling Point 222.8ºC at 760 mmHg
Molecular Formula CF3KO2S Melting Point 236-241ºC
MSDS N/A Flash Point 88.5ºC

 Names

Name potassium,trifluoromethanesulfinate
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 222.8ºC at 760 mmHg
Melting Point 236-241ºC
Molecular Formula CF3KO2S
Molecular Weight 172.16800
Flash Point 88.5ºC
Exact Mass 171.92100
PSA 59.34000
LogP 1.25100

 MSDS

Name: Trifluoromethanesulphinic acid potassium salt Material Safety Data Sheet
Synonym:
CAS: 41804-89-1
Section 1 - Chemical Product MSDS Name:Trifluoromethanesulphinic acid potassium salt Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
41804-89-1 Trifluoromethanesulphinic acid potassi 255-556-9
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 41804-89-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 170 - 171 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 172.20

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 41804-89-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trifluoromethanesulphinic acid potassium salt - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 41804-89-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 41804-89-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 41804-89-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
HS Code 2930909090

 Synthetic Route

~81%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Central Glass Company, Limited; KASHIWABA, Takashi; NANMYO, Tsutomu; TAKENAKA, Yoichi Patent: EP2543663 A1, 2013 ; Location in patent: Paragraph 0060; 0061; 0062 ;

~95%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Goto, Yoshihiko; Sakai, Shigenori; Sakaguchi, Hiroaki Patent: US2001/31891 A1, 2001 ;

~52%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Besson, Bernard Patent: US2009/216036 A1, 2009 ; Location in patent: Page/Page column 4-5 ;

~94%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.2, page 1 - 48

~%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Hendrickson,J.B. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 3412 - 3413

~51%

potassium,trifluoromethanesulfinate Structure

potassium,trifl...

CAS#:41804-89-1

Literature: Langlois, Bernard R.; Billard, Thierry; Mulatier, Jean-Christophe; Yezeguelian, Catherine Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 851 - 856

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

potassium salt of trifluoromethylsulfinic acid
potassium trifluoromethylsulphinate
Potassium triflinate
Potassium trifluoromethanesulphinate
PC5712
EINECS 255-556-9
potassium trifluoromethylsulfinate
potassium trifluoromethane sulfinate