2-Bromo-3-nitrotoluene

Modify Date: 2024-01-02 13:56:59

2-Bromo-3-nitrotoluene Structure
2-Bromo-3-nitrotoluene structure
 Common Name 2-Bromo-3-nitrotoluene
CAS Number 41085-43-2 Molecular Weight 216.032
Density 1.6±0.1 g/cm3 Boiling Point 282.4±0.0 °C at 760 mmHg
Molecular Formula C7H6BrNO2 Melting Point 38-41 °C(lit.)
MSDS Chinese USA Flash Point 104.5±21.8 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 2-Bromo-3-nitrotoluene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 282.4±0.0 °C at 760 mmHg
Melting Point 38-41 °C(lit.)
Molecular Formula C7H6BrNO2
Molecular Weight 216.032
Flash Point 104.5±21.8 °C
Exact Mass 214.958176
PSA 45.82000
LogP 2.98
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.593
Storage condition Room temperature.

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2904909090

 Synthetic Route

2-Methyl-6-nitroaniline structure

2-Methyl-6-nitr...

CAS#:570-24-1

~93%

2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2
Literature: Holzwarth, Richard; Bartsch, Richard; Cherkaoui, Zoubair; Solladie, Guy European Journal of Organic Chemistry, 2005 , # 16 p. 3536 - 3541
Acetamide,N-(2-methyl-6-nitrophenyl)- structure

Acetamide,N-(2-...

CAS#:59907-22-1

~%

2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2
Literature: Liedholm,B. Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1976 , vol. 30, p. 141 - 149
2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5

~%

2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2
Literature: Geerling; Wibaut Recueil des Travaux Chimiques des Pays-Bas, 1934 , vol. 53, p. 1011,1016, 1025
2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5

~20%

1-Bromo-2-methyl-4-nitrobenzene structure

1-Bromo-2-methy...

CAS#:7149-70-4
2-Bromo-4-nitrotoluene structure

2-Bromo-4-nitro...

CAS#:7745-93-9
2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2

Detail
Literature: Manglik, Ajay K.; Moodie, Roy B.; Schofield, Kenneth; Tobin, Geoffrey D.; Coombes, Robert G.; Hadjigeorgiu, Panicos Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1606 - 1616
O-ACETOTOLUIDIDE structure

O-ACETOTOLUIDIDE

CAS#:120-66-1

~%

2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2
Literature: Liedholm,B. Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1976 , vol. 30, p. 141 - 149
2-Bromo-3-methylaniline structure

2-Bromo-3-methy...

CAS#:54879-20-8

~%

2-Bromo-3-nitrotoluene Structure

2-Bromo-3-nitro...

CAS#:41085-43-2
Literature: Manglik, Ajay K.; Moodie, Roy B.; Schofield, Kenneth; Tobin, Geoffrey D.; Coombes, Robert G.; Hadjigeorgiu, Panicos Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1606 - 1616
2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5
Dinitro-ortho-cresol structure

Dinitro-ortho-cresol

CAS#:534-52-1
nitric acid structure

nitric acid

CAS#:7697-37-2

~%

1-Bromo-2-methyl-4-nitrobenzene structure

1-Bromo-2-methy...

CAS#:7149-70-4
Detail
Literature: Geerling Recueil des Travaux Chimiques des Pays-Bas, 1935 , vol. 54, p. 235,238 Full Text Show Details Geerling; Wibaut Recueil des Travaux Chimiques des Pays-Bas, 1934 , vol. 53, p. 1011,1016, 1025
2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5
nitric acid structure

nitric acid

CAS#:7697-37-2
o-cresol structure

o-cresol

CAS#:95-48-7

~%

1-Bromo-2-methyl-4-nitrobenzene structure

1-Bromo-2-methy...

CAS#:7149-70-4
Detail
Literature: Geerling Recueil des Travaux Chimiques des Pays-Bas, 1935 , vol. 54, p. 235,238 Full Text Show Details Geerling; Wibaut Recueil des Travaux Chimiques des Pays-Bas, 1934 , vol. 53, p. 1011,1016, 1025
2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5
nitric acid structure

nitric acid

CAS#:7697-37-2
Phenol structure

Phenol

CAS#:108-95-2

~%

1-Bromo-2-methyl-4-nitrobenzene structure

1-Bromo-2-methy...

CAS#:7149-70-4
Detail
Literature: Geerling Recueil des Travaux Chimiques des Pays-Bas, 1935 , vol. 54, p. 235,238 Full Text Show Details Geerling; Wibaut Recueil des Travaux Chimiques des Pays-Bas, 1934 , vol. 53, p. 1011,1016, 1025

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
1-Bromo-4-methyl-2-nitro-benzene.

Acta Crystallogr. Sect. E Struct. Rep. Online 67(10) , o2641-o2641., (2011)

In the title compound, C(7)H(6)BrNO(2), the dihedral angle between the nitro group and the phenyl ring is 14.9 (11)°.
Ullmann Synthesis of Six Dimethyldinitrobiphenyls and their Reduction to the Corresponding Diaminodimethylbiphenyls1. Carlin RB and Foltz GE.

J. Am. Chem. Soc. 78(9) , 1997-2000, (1956)
675. Synthesis of fluoranthenes. Part IV. 10-and 11-Substituted fluoranthenes. HorwoodáTucker S.

J. Chem. Soc. , 3213-16, (1949)

 Synonyms

2-Bromo-1-methyl-3-nitrobenzene
2-Bromo-3-nitrotoluene
Benzene, 2-bromo-1-methyl-3-nitro-
MFCD00134555
2-brom-1-methyl-3-nitrobenzol
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