Lithium bis(trimethylsilyl)amide

Modify Date: 2024-01-02 11:29:59

Lithium bis(trimethylsilyl)amide Structure
Lithium bis(trimethylsilyl)amide structure
Common Name Lithium bis(trimethylsilyl)amide
CAS Number 4039-32-1 Molecular Weight 167.326
Density 0.891 g/mL at 25 °C Boiling Point 55-56 °C
Molecular Formula C6H18LiNSi2 Melting Point 73°C
MSDS Chinese Flash Point 48 °F
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Lithium bis(trimethylsilyl)amide
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.891 g/mL at 25 °C
Boiling Point 55-56 °C
Melting Point 73°C
Molecular Formula C6H18LiNSi2
Molecular Weight 167.326
Flash Point 48 °F
Exact Mass 167.113785
PSA 3.24000
LogP 2.42250
Index of Refraction n20/D 1.425(lit.)
Storage condition below 5° C
Water Solubility hydrolysis

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H225-H314
Supplemental HS May form explosive peroxides., Reacts violently with water.
Precautionary Statements P210-P280-P305 + P351 + P338-P310
Hazard Codes F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
Risk Phrases R11;R20;R35;R51/53;R65;R67
Safety Phrases S9-S16-S26-S29-S33-S36/37/39-S45-S61-S62-S57-S43
RIDADR UN 2925 4.1/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 4.3
HS Code 2931900090

 Synthetic Route

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles29

More Articles
Design, synthesis and biological evaluation of small molecules as potent glucosidase inhibitors.

Eur. J. Med. Chem. 100 , 188-96, (2015)

Herein we have reported design, synthesis and in vitro biological evaluation of a library of bicyclic lactams that led to the discovery of compounds 6 and 7 as a novel class of α-glucosidase inhibitor...

Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.

J. Colloid. Interface Sci. 356(1) , 298-302, (2011)

The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and ...

Independent Composition and Size Control for Highly Luminescent Indium-Rich Silver Indium Selenide Nanocrystals.

ACS Nano 9 , 11134-42, (2015)

Ternary I-III-VI nanocrystals, such as silver indium selenide (AISe), are candidates to replace cadmium- and lead-based chalcogenide nanocrystals as efficient emitters in the visible and near IR, but,...

 Synonyms

Lithium 1,1,1,3,3,3-hexamethyldisilazan-2-ide
Lithium hexamethyldisilazide
EINECS 223-725-6
LITHIUM, (BIS(TRIMETHYLSILYL)AMINO)-
MFCD00008261
Hexamethyldisilazane lithium salt
Lithium, [bis(trimethylsilyl)amino]-
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, lithium salt (1:1)
Lithium bis(trimethylsilyl)amide
Lithium bis(trimet
lithium,bis(trimethylsilyl)azanide