4-Amino-2,2,6,6-tetramethylpiperidine

Modify Date: 2024-01-02 16:09:57

4-Amino-2,2,6,6-tetramethylpiperidine Structure
4-Amino-2,2,6,6-tetramethylpiperidine structure
Common Name 4-Amino-2,2,6,6-tetramethylpiperidine
CAS Number 36768-62-4 Molecular Weight 156.268
Density 0.8±0.1 g/cm3 Boiling Point 188.5±8.0 °C at 760 mmHg
Molecular Formula C9H20N2 Melting Point 16-18 °C(lit.)
MSDS Chinese USA Flash Point 72.2±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name 4-Amino-2,2,6,6-tetramethylpiperidine
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.8±0.1 g/cm3
Boiling Point 188.5±8.0 °C at 760 mmHg
Melting Point 16-18 °C(lit.)
Molecular Formula C9H20N2
Molecular Weight 156.268
Flash Point 72.2±0.0 °C
Exact Mass 156.162643
PSA 38.05000
LogP 1.60
Vapour Pressure 0.6±0.4 mmHg at 25°C
Index of Refraction 1.433
Water Solubility soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TM4290100
CHEMICAL NAME :
Piperidine, 4-amino-2,2,6,6-tetramethyl-
CAS REGISTRY NUMBER :
36768-62-4
BEILSTEIN REFERENCE NO. :
0105038
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C9-H20-N2
MOLECULAR WEIGHT :
156.31
WISWESSER LINE NOTATION :
T6NTJ B1 B1 DZ F1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
906 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),53,1984

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H290-H302-H314-H412
Precautionary Statements P273-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful;
Risk Phrases R22;R36/37/38
Safety Phrases S26-S36/37-S45-S36/37/39
RIDADR UN 2735 8/PG 3
WGK Germany 2
RTECS TM4290100
Packaging Group III
Hazard Class 8
HS Code 29333999

 Synthetic Route

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles2

More Articles
Synthesis of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate and 4-acetamido-(2,2,6,6-tetramethyl-piperidin-1-yl)oxyl and their use in oxidative reactions.

Nat. Protoc. 8 , 666, (2013)

We describe the synthesis of the lesser-known stoichiometric oxidation reagent 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1, Bobbitt's salt), as well as of 4-acetamido-...

[Comparative characteristics of the toxicity, safety and nature of the biological effect on the body of 4-hydroxy-2,2,6,6-tetramethylpiperidine and 4-amino-2,2,6,6-tetramethylpiperidine].

Gig. Tr. Prof. Zabol. (5) , 53-4, (1984)

 Synonyms

4-Piperidinamine, 2,2,6,6-tetramethyl-
2,2,6,6-Tetramethyl-4-aminopiperidine
UNII-ETF220Q65R
2,2,6,6-tetramethylpiperidin-4-amine
4-Amino-2,2,6,6-tetramethylpiperidine
2,2,6,6-tetramethyl-4-piperidylamine
EINECS 253-197-2
Triacetonediamine
MFCD00005984
4-Amino-2,2,6,6-tetramethyl-piperidine
4-Amion-2,2,6,6-Tetramentylniperidine