2-Methoxyethyl acrylate

Modify Date: 2024-01-08 11:10:22

2-Methoxyethyl acrylate Structure
2-Methoxyethyl acrylate structure
Common Name 2-Methoxyethyl acrylate
CAS Number 3121-61-7 Molecular Weight 130.14200
Density 1.012 g/mL at 25 °C(lit.) Boiling Point 56 °C12 mm Hg(lit.)
Molecular Formula C6H10O3 Melting Point -30°C
MSDS Chinese USA Flash Point 60 ºC
Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08
Signal Word Danger

 Names

Name 2-methoxyethyl prop-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.012 g/mL at 25 °C(lit.)
Boiling Point 56 °C12 mm Hg(lit.)
Melting Point -30°C
Molecular Formula C6H10O3
Molecular Weight 130.14200
Flash Point 60 ºC
Exact Mass 130.06300
PSA 35.53000
LogP 0.36200
Index of Refraction n20/D 1.427(lit.)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KL6000000
CHEMICAL NAME :
Ethanol, 2-methoxy-, acrylate
CAS REGISTRY NUMBER :
3121-61-7
BEILSTEIN REFERENCE NO. :
1754333
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H10-O3
MOLECULAR WEIGHT :
130.16
WISWESSER LINE NOTATION :
1U1VO2O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
810 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
250 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 9/17/1969 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5200 mg/kg
SEX/DURATION :
female 7-14 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB86-197605
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5200 mg/kg
SEX/DURATION :
female 6-13 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth)
REFERENCE :
TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1980- Volume(issue)/page/year: 7,29,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7024 No. of Facilities: 4 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1220 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS06 GHS08
GHS02, GHS05, GHS06, GHS08
Signal Word Danger
Hazard Statements H226-H302-H311 + H331-H314-H317-H360FD-H373-H412
Precautionary Statements P201-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313-P403 + P233
Target Organs Blood, Epididymus, Testes
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic;
Risk Phrases R20/22;R24;R60;R61
Safety Phrases S16-S26-S36/37/39-S45-S53
RIDADR UN 1992 3/PG 3
WGK Germany 1
RTECS KL6000000
Packaging Group II
Hazard Class 6.1
HS Code 29161290

 Synthetic Route

~%

2-Methoxyethyl acrylate Structure

2-Methoxyethyl ...

CAS#:3121-61-7

Literature: Tetrahedron, , vol. 48, # 31 p. 6371 - 6384

~%

2-Methoxyethyl acrylate Structure

2-Methoxyethyl ...

CAS#:3121-61-7

Literature: Journal of Organic Chemistry, , vol. 14, p. 1094,1095, 1097 US2396434 , ;

~%

2-Methoxyethyl acrylate Structure

2-Methoxyethyl ...

CAS#:3121-61-7

Literature: Journal of Organic Chemistry, , vol. 14, p. 1094,1095, 1097 US2396434 , ;

 Customs

HS Code 2916129000
Summary 2916129000 other esters of acrylic acid VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles1

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RAFT copolymerization of itaconic anhydride and 2-methoxyethyl acrylate: a multifunctional scaffold for preparation of “clickable” gold nanoparticles. Javakhishvili I, et al.

Chem. Commun. (Camb.) 49 , 4803-4805, (2013)

 Synonyms

Ethylene Glycol Monomethyl Ether Acrylate
n-methoxyethyl acrylate
Acrylic Acid 2-Methoxyethyl Ester
Ethylene Glycol Methyl Ether Acrylate
Methyl cellosolve acrylate
Ethylene glycol methyl ether acrylate,stabilized
acrylic acid 2-methoxy-ethyl ester
EINECS 221-499-3
2-Methoxyethoxy acrylate
2-Propenoic acid,2-methoxyethyl ester
2-Methoxyethanol,acrylate
2-METHOXYETHYL ACRYLATE
1-Acryloyloxy-2-methoxy-aethan
Methoxyethyl acrylate
MFCD00048149
Sipomer MCA