Bicyclo[2.2.1]hept-2-ene,5-ethenyl-

Modify Date: 2024-01-10 12:54:20

Bicyclo[2.2.1]hept-2-ene,5-ethenyl- Structure
Bicyclo[2.2.1]hept-2-ene,5-ethenyl- structure
Common Name Bicyclo[2.2.1]hept-2-ene,5-ethenyl-
CAS Number 3048-64-4 Molecular Weight 120.19200
Density 0.841 g/mL at 25 °C(lit.) Boiling Point 141 °C(lit.)
Molecular Formula C9H12 Melting Point −80 °C(lit.)
MSDS Chinese USA Flash Point 82 °F
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name 5-vinyl-2-norbornene
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.841 g/mL at 25 °C(lit.)
Boiling Point 141 °C(lit.)
Melting Point −80 °C(lit.)
Molecular Formula C9H12
Molecular Weight 120.19200
Flash Point 82 °F
Exact Mass 120.09400
LogP 2.38460
Vapour density >1 (vs air)
Vapour Pressure 6 mm Hg ( 20 °C)
Index of Refraction n20/D 1.481(lit.)
Storage condition 0-6°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RC0350000
CHEMICAL NAME :
2-Norbornene, 5-vinyl-
CAS REGISTRY NUMBER :
3048-64-4
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C9-H12
MOLECULAR WEIGHT :
120.21
WISWESSER LINE NOTATION :
L55 A CUTJ F1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536177
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536177 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5190 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2231 ppm/4H
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - tremor Behavioral - ataxia
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536315
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5667 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(10),52,1974
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
17700 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(10),52,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
15900 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
150 ppm/6H/11D
TOXIC EFFECTS :
Liver - changes in liver weight Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536315
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1860 mg/m3/5W-I
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(10),52,1974
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1860 mg/m3/5W-I
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(10),52,1974

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319
Precautionary Statements P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases R10;R20;R36/38;
Safety Phrases S16-S26-S36/37
RIDADR UN 1992 3/PG 3
WGK Germany 2
RTECS RC0350000
Packaging Group III
Hazard Class 3.2
HS Code 2902199090

 Synthetic Route

Bicyclo[2.2.1]hept-2-ene,5-ethenyl- Structure

Bicyclo[2.2.1]h...

CAS#:3048-64-4

~%

Bicyclo[2.2.1]hept-2-ene,5-ethenyl- Structure

Bicyclo[2.2.1]h...

CAS#:3048-64-4

Literature: Bulletin of the Chemical Society of Japan, , vol. 60, p. 1954 - 1956

~%

Bicyclo[2.2.1]hept-2-ene,5-ethenyl- Structure

Bicyclo[2.2.1]h...

CAS#:3048-64-4

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 314, p. 467 - 482

~%

Bicyclo[2.2.1]hept-2-ene,5-ethenyl- Structure

Bicyclo[2.2.1]h...

CAS#:3048-64-4

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 314, p. 467 - 482

 Customs

HS Code 2902199090
Summary 2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

 Articles1

More Articles
Mechanistic investigation of the isomerization of 5-vinyl-2-norbornene.

J. Org. Chem. 71(3) , 911-4, (2006)

The isomerization reaction of 5-vinyl-2-norbornene (VNB) to 5-ethylidene-2-norbornene (ENB) has been performed using a catalytic system consisting of an alkali metal hydride and an amine. Among variou...

 Synonyms

5-vinylbicyclo[2.2.1]hept-2-ene
2-vinyl-5-norbornene
5-vinylnorborn-2-ene
Vinylnorbornene
5-vinyl-2-norbornen
VINYL BICYCLOHEPTENE
2-Vinylnorbornene
5-vinylnorborene
5-Vinyl-2-norbornene,stabilized
endo-5-vinylbicyclo<2.2.1>hept-2-ene
MFCD00080691
EINECS 221-259-8
5-vinylbicyclo[2.2.1]hepta-2-ene
VBCH
5-Vinylnorbornene
5-vinylnorbernene
5-Vinyl-2-norbornene