tert-Butyl (2-hydroxyphenyl)carbamate

Modify Date: 2024-01-03 14:11:51

tert-Butyl (2-hydroxyphenyl)carbamate Structure
tert-Butyl (2-hydroxyphenyl)carbamate structure
Common Name tert-Butyl (2-hydroxyphenyl)carbamate
CAS Number 186663-74-1 Molecular Weight 209.24200
Density 1.182g/cm3 Boiling Point 265.6ºC at 760 mmHg
Molecular Formula C11H15NO3 Melting Point 140-144ºC(lit.)
MSDS Chinese USA Flash Point 114.4ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name tert-butyl N-(2-hydroxyphenyl)carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.182g/cm3
Boiling Point 265.6ºC at 760 mmHg
Melting Point 140-144ºC(lit.)
Molecular Formula C11H15NO3
Molecular Weight 209.24200
Flash Point 114.4ºC
Exact Mass 209.10500
PSA 62.05000
LogP 2.75280
Vapour Pressure 0.00552mmHg at 25°C
Index of Refraction 1.569

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H317-H319
Precautionary Statements P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/38
Safety Phrases S26
RIDADR NONH for all modes of transport
HS Code 2924299090

 Synthetic Route

~99%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Chankeshwara, Sunay V.; Chakraborti, Asit K. Tetrahedron Letters, 2006 , vol. 47, # 7 p. 1087 - 1091

~87%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Porzelle, Achim; Woodrow, Michael D.; Tomkinson, Nicholas C. O. European Journal of Organic Chemistry, 2008 , # 30 p. 5135 - 5143

~83%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Porzelle, Achim; Woodrow, Michael D.; Tomkinson, Nicholas C. O. European Journal of Organic Chemistry, 2008 , # 30 p. 5135 - 5143

~89%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Chandrasekhar; Narsihmulu; Jagadeshwar Synlett, 2002 , # 5 p. 771 - 772

~89%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Arifuddin, M.; Lakshmikant, N.; Rajasekar, N.; Shinde, D. B. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2012 , vol. 51, # 8 p. 1168 - 1172,5

~84%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Dandepally, Srinivasa Reddy; Williams, Alfred L. Tetrahedron Letters, 2009 , vol. 50, # 9 p. 1071 - 1074

~43%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Shindo, Kazutoshi; Nakamura, Ryoko; Chinda, Ikuko; Ohnishi, Yasuo; Horinouchi, Sueharu; Takahashi, Haruko; Iguchi, Kazuo; Harayama, Shigeaki; Furukawa, Kensuke; Misawa, Norihiko Tetrahedron, 2003 , vol. 59, # 11 p. 1895 - 1900

~72%

tert-Butyl (2-hydroxyphenyl)carbamate Structure

tert-Butyl (2-h...

CAS#:186663-74-1

Literature: Porzelle, Achim; Woodrow, Michael D.; Tomkinson, Nicholas C. O. European Journal of Organic Chemistry, 2008 , # 30 p. 5135 - 5143

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

2-OH-Ph-NH2
tert-butyl-N-(2-hydroxyphenyl)carbamate
2-t-butoxycarbonylamino-1-hydroxybenzene
N-tert-Butoxycarbonyl-2-aminophenol
o-[N-(tert-butoxycarbonyl)amino]phenol
N-Boc-2-aminophenol
(2-hydroxy-phenyl)-carbamic acid tert-butyl ester
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