Praseodymium (III) 2,4-pentanedionate

Modify Date: 2024-01-09 00:04:47

Praseodymium (III) 2,4-pentanedionate Structure
Praseodymium (III) 2,4-pentanedionate structure
Common Name Praseodymium (III) 2,4-pentanedionate
CAS Number 14553-09-4 Molecular Weight 310.34200
Density N/A Boiling Point 138.4ºC at 760mmHg
Molecular Formula C16H22O6 Melting Point 130ºC (dec.)(lit.)
MSDS N/A Flash Point 43.1ºC

 Names

Name praseodymium(iii) acetylacetonate hydrate
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 138.4ºC at 760mmHg
Melting Point 130ºC (dec.)(lit.)
Molecular Formula C16H22O6
Molecular Weight 310.34200
Flash Point 43.1ºC
Exact Mass 310.14200
PSA 78.90000
LogP 2.79820
Appearance of Characters Powder | Off-white to pale green
Vapour Pressure 0.174mmHg at 25°C

 MSDS


Section 1: Product Identification
Chemical Name:Praseodymium (III) acetylacetonate hydrate (99.9%-Pr) (REO)
CAS Registry Number:14553-09-4
Formula:Pr(CH3COCHCOCH3)3.XH2O
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Tris(2,4-pentanedionato)praseodymium (III) hydrate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14553-09-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the respiratory tract, skin and eyes.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:pale green powder
Molecular Weight:438.23
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:halogens and oxidizing agents
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases 26-36
WGK Germany 3

 Synonyms

Tris-(2,4-pentanedionato)-praseodymium
PRASEODYMIUM ACETYL ACETONATE
PRASEODYMIUM ACETYLACETONATE HYDRATE
PRASEODYMIUM 2,4-PENTANEDIONATE
PRASEODYMIUM(III) ACETYLACETONATE
Praseodymium (III) 2,4-pentanedionate